全文获取类型
收费全文 | 984篇 |
免费 | 80篇 |
国内免费 | 912篇 |
专业分类
化学 | 1871篇 |
晶体学 | 27篇 |
力学 | 6篇 |
综合类 | 11篇 |
物理学 | 61篇 |
出版年
2024年 | 3篇 |
2023年 | 9篇 |
2022年 | 27篇 |
2021年 | 47篇 |
2020年 | 55篇 |
2019年 | 45篇 |
2018年 | 56篇 |
2017年 | 42篇 |
2016年 | 63篇 |
2015年 | 48篇 |
2014年 | 43篇 |
2013年 | 88篇 |
2012年 | 88篇 |
2011年 | 66篇 |
2010年 | 60篇 |
2009年 | 70篇 |
2008年 | 79篇 |
2007年 | 65篇 |
2006年 | 90篇 |
2005年 | 88篇 |
2004年 | 92篇 |
2003年 | 88篇 |
2002年 | 69篇 |
2001年 | 71篇 |
2000年 | 65篇 |
1999年 | 64篇 |
1998年 | 62篇 |
1997年 | 69篇 |
1996年 | 52篇 |
1995年 | 55篇 |
1994年 | 47篇 |
1993年 | 47篇 |
1992年 | 22篇 |
1991年 | 6篇 |
1990年 | 11篇 |
1989年 | 5篇 |
1988年 | 7篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 5篇 |
1983年 | 2篇 |
1959年 | 1篇 |
排序方式: 共有1976条查询结果,搜索用时 187 毫秒
101.
Water vapor, methanol, and argon adsorption isotherms, as well as the heat of adsorption of ammonia, methanol, and carbon dioxide have been determined on zeolite types A, ZK-4, and ZK-5. The results are explained by the distribution and the bond lengths of cations in the zeolite crystal lattice. It was shown that the exchange of 10–15% of the Na+ ions with Li+ in zeolite ZK-5 leads to a deformation of the 8-membered ring impeding the diffusion of adsorbed molecules. Cations contained in the 8-membered ZK-5 zeolite ring are bound more strongly to the framework, than in zeolite NaA, resulting in their smaller adsorption capacity.I. V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199164 St. Petersburg, Russia. Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 11, pp. 2494–2500, November, 1992. 相似文献
102.
Effects of Calcination Temperature on the Acidity and Catalytic Performances of HZSM-5 Zeolite Catalysts for the Catalytic Cracking of n-Butane 下载免费PDF全文
The acidic modulations of a series of HZSM-5 catalysts were successfully made by calcination at different treatment temperatures, i.e. 500, 600, 650, 700 and 800 ℃, respectively. The results indicated that the total acid amounts, their density and the amount of B-type acid of HZSM-5 catalysts rapidly decreased, while the amounts of L-type acid had almost no change and thus the ratio of L/B was obviously enhanced with the increase of calcination temperature (excluding 800 ℃). The catalytic performances of modified HZSM-5 catalysts for the cracking of n-butane were also investigated. The main properties of these catalysts were characterized by means of XRD, N2 adsorption at low temperature, NH3-TPD, FTIR of pyridine adsorption and BET surface area measurements. The results showed that HZSM-5 zeolite pretreated at 800 ℃ had very low catalytic activity for n-butane cracking. In the calcination temperature range of 500-700 ℃, the total selectivity to olefins, propylene and butene were increased with the increase of calcination temperature, while, the selectivity for arene decreased with the calcination temperature.The HZSM-5 zeolite calcined at 700 ℃ produced light olefins with high yield, at the reaction temperature of 650 ℃ the yields of total olefins and ethylene were 52.8% and 29.4%, respectively. Besides, the more important role is that high calcination temperature treatment improved the duration stability of HZSM-5zeolites. The effect of calcination temperature on the physico-chemical properties and catalytic performance of HZSM-5 for cracking of n-butane was explored. It was found that the calcination temperature had large effects on the surface area, crystallinity and acid properties of HZSM-5 catalyst, which further affected the catalytic performance for n-butane cracking. 相似文献
103.
The adsorption isotherms of H2S in selected adsorbents were determined at 298 K, at relative pressures up to about 0.005, aiming the use of these materials
in the removal of that pollutant from the museums atmosphere. The Dubinin-Astakhov equation adjusts very well the experimental
results, although one cannot interpret the pre-exponential factor w0 as the limiting adsorbed amount. The parameter E, related with the adsorption energy, and the parameter n, that can be associated with the surface heterogeneity of the adsorbents, are correlated and the first is also correlated
with the adsorbed amounts. It was not found any expectable relationship between the adsorbed amounts and textural parameters
of the adsorbents such as the specific surface area or the microporous volume. This points out that the adsorption of H2S is highly specific. In general, 13X and Y sodium zeolites seem to be the most effective adsorbents, but at lowest tested
pressures, near the concentrations found at museums, a pillared clay prepared from a Wyoming montmorillonite seems to be more
efficient. 相似文献
104.
ZSM-5分子筛吸附分离对二乙苯的研究 总被引:1,自引:0,他引:1
本文用动态法就对二乙苯在ZSM-5分子筛上的吸附进行了研究,考察了温度、脉冲进料量、解吸剂的流速、解吸剂的性质等对分离效果的影响,确定了最佳操作条件:温度为200℃~230℃,常压,以甲苯为解吸剂,解吸剂流量 250~350Kg/m2·h,对二乙苯的单程收率为 60%,纯度>95%。 相似文献
105.
FTIR-spectroscopic investigations of catalytic reactions yield detailed information about the interaction of adsorbed molecules with the catalyst and kinetic data of the surface reaction, if the participating molecules show vibrations whose position and intensity in the IR-spectrum depend on the sorption state and the quantity adsorbed. In this paper, the possibilities and limitations of the method are represented by two examples. 相似文献
106.
107.
M. Reháková A. Sopková J. Lokaj 《Journal of inclusion phenomena and macrocyclic chemistry》1992,14(1):47-54
The aim of this study was the preparation of natural zeolitic materials doped with iodine and its ions. Natural zeolite from an East Slovakian deposit was used. The content of iodine in the zeolitic products depended on the experimental conditions used for the preparation. The products and their intermediates obtained at 100, 200, 400 and 900°C were identified. 相似文献
108.
采用两种不同的脱铝方法对HZSM-5分子筛进行了预处理,并利用MAS NMR和吸附吡啶的FT-IR对分子筛的结构和酸性质进行了表征,考察了分子筛的脱铝程度对Mo基催化剂上甲烷芳构化反应性能的影响.结果表明,HZSM-5分子筛的酸性过强或B酸量不足,均会导致催化剂严重积炭,但积炭成因不同.母体HZSM-5分子筛上的强B酸中心的存在可促使催化剂上反应中间物种深度脱氢,造成催化剂在反应过程中严重积炭.经水热处理的HZSM-5分子筛,骨架铝脱出严重,造成B酸活性中心不足以及部分微孔阻塞,不利于C2中间物种芳构化,导致芳烃选择性显著降低.经高温N2处理的HZSM-5分子筛,骨架铝脱出相对缓和,在消除母体分子筛上强B酸中心的同时,保留了较多的弱B酸中心,既可满足C2中间物种芳构化反应的需要,又可有效抑制催化剂积炭,导致甲烷芳构化反应性能显著改善. 相似文献
109.
在不同温度下,用水蒸气对P-ZSM-5催化剂进行了处理,利用XRD、NH3-TPD、比表面和孔径物理吸附仪等手段对催化剂进行了表征,研究了水蒸气处理对P-ZSM-5催化1-丁烯裂解反应性能的影响.实验结果表明:P-ZSM-5催化剂具有良好的水热稳定性;合适的水蒸气处理,有利于催化剂孔容和孔径的增加;水蒸气处理降低了P-ZSM-5催化剂的酸量和酸强度,明显提高了丁烯裂解生成丙烯的选择性、收率和催化剂的抗积炭性能.最佳的水蒸气处理温度为580℃,P-ZSM-5催化剂催化1-丁烯裂解反应的丙烯选择性为39.4%,收率为34.2%. 相似文献
110.